Phosphasteroids - I. Cycloaddition reactions of phospholenes with various dienes.

✍ Scribed by Y. Kashman; O. Awerbouch

• Book ID: 104216208
• Publisher: Elsevier Science
• Year: 1973
• Tongue: French
• Weight: 247 KB
• Volume: 14
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)79816-9

✦ Synopsis

In connection with our interest in the synthesis of phosphorus heterocycles and phosphasteroids, we wish to report a facile total synthesis of the 17phosphasteroidal skeleton, a synthesis which is based on the cycloadditivn of a suitable phospholenic moiety to l-vinyl-b-methoxy-