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Efficient Higher-Order Cycloaddition Reactions of 8,8-Dicyanoheptafulvene with Dienes.

✍ Scribed by Vijay Nair; K. Gopalakrishnan Abhilash; Akkattu T. Biju; Eringathodi Suresh


Publisher
John Wiley and Sons
Year
2007
Weight
22 KB
Volume
38
Category
Article
ISSN
0931-7597

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Reactions of 1,8-Diheterocyclotetradeca-
✍ Volker Wolfart; Matthias Ramming; Rolf Gleiter; Bernhard Nuber; Hans Pritzkow; F πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 276 KB πŸ‘ 1 views

The following monocyclic and bicyclic 14-membered diynes all cases we obtained an intramolecular cyclobutadiene complex stabilized with a CpCo fragment (15-26). For 3 we were treated with [CpCo(cod)]: 1-oxacyclotetradeca-4,11diyne (2), 1,8-dioxacyclotetradeca-4,11-diyne (3), cyclotetra-could isolate