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Phosphacarborane Chemistry: The Synthesis of the Parent Phosphadicarbaboranes nido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]−, and Their 10-Cl Derivatives − Analogs of the Cyclopentadienide Anion

✍ Scribed by Bohumil Štíbr; Josef Holub; Mario Bakardjiev; Drahomír Hnyk; Oleg L. Tok; Wolfgang Milius; Bernd Wrackmeyer

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
185 KB
Volume
2002
Category
Article
ISSN
1434-1948

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✍ Rosario Núñez; Clara Viñas; Francesc Teixidor; Ma Mar Abad 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB

## Abstract Reaction of [RuH(AcO)(PPh~3~)~3~] and [NMe~4~][7,8‐(PPh~2~)~2~‐7,8‐C~2~B~9~H~10~] in methanol yields [RuH(7,8‐(PPh~2~)~2~‐7,8‐C~2~B~9~H~10~)(PPh~3~)~2~] (1). The reaction of [RuCl~2~(PPh~3~)~3~] and [NMe~4~][7,8‐(PPh~2~)~2~‐7,8‐C~2~B~9~H~10~] in a 1 : 1 or 1 : 2 ratio in methanol yields