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Coordination of the nido-Carboranyldiphosphine Ligand to Ruthenium(II): The First Example of the Tricoordinating Capacity of the 7,8-(PPh2) 2-7,8-C2B9H10 Moiety.

✍ Scribed by Rosario Nunez; Clara Vinas; Francesc Teixidor; M. Mar Abad

Publisher
John Wiley and Sons
Year
2003
Weight
54 KB
Volume
34
Category
Article
ISSN
0931-7597

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Coordination of the nido-carboranyldipho
Coordination of the nido-carboranyldiphosphine ligand to ruthenium(II): the first example of the tricoordinating capacity of the 7,8-(PPh2)2-7,8-C2B9H10 moiety
✍ Rosario Núñez; Clara Viñas; Francesc Teixidor; Ma Mar Abad 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB 👁 1 views

## Abstract Reaction of [RuH(AcO)(PPh~3~)~3~] and [NMe~4~][7,8‐(PPh~2~)~2~‐7,8‐C~2~B~9~H~10~] in methanol yields [RuH(7,8‐(PPh~2~)~2~‐7,8‐C~2~B~9~H~10~)(PPh~3~)~2~] (1). The reaction of [RuCl~2~(PPh~3~)~3~] and [NMe~4~][7,8‐(PPh~2~)~2~‐7,8‐C~2~B~9~H~10~] in a 1 : 1 or 1 : 2 ratio in methanol yields