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Phonon-assisted energy up-conversion process of ions doped in crystal

✍ Scribed by Ta-Ryeong Park


Book ID
104093825
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
472 KB
Volume
150
Category
Article
ISSN
0038-1098

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✦ Synopsis


Er 3+ ions doped in KYF 4 crystal emit blue photoluminescence around 406 nm by energy up-conversion process when excited by 532 or 488 nm laser. By measuring the temperature dependence of up-converted luminescence, we found that the up-conversion process is enhanced with increasing temperature, which is an indication that phonons are assisting the process. This observation is supported by the fact that the energy transfer responsible for the up-conversion involves two transitions that have an energy mismatch.


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**Optically nonlinear single crystals of potassium hydrogen phthalate** were grown in the presence of a variety of laser dyes. Up‐conversion fluorescence (as shown in the Figure) in the visible part of the spectrum was observed as a result of two excitation mechanisms involving trapped, oriented lum