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Pheromone synthesis. Part 245: Synthesis and chromatographic analysis of the four stereoisomers of 4,8-dimethyldecanal, the male aggregation pheromone of the red flour beetle, Tribolium castaneum

✍ Scribed by Kazuaki Akasaka; Shigeyuki Tamogami; Richard W. Beeman; Kenji Mori


Book ID
108283451
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
549 KB
Volume
67
Category
Article
ISSN
0040-4020

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📜 SIMILAR VOLUMES


Deuterated analogues of 4,8-dimethyldeca
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## Abstract To elucidate the deuterium isotope effect (DIE) in pheromonal activity and to investigate the biosynthetic pathway of 4,8‐dimethyldecanal (4,8‐DMD; **1**), the aggregation pheromone of the red flour beetle (__Tribolium castaneum__), deuterated analogues of 4,8‐DMDs (**2**, **3**, **4**,

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## Abstract (4__S__,8__S__)‐ and (4__S__,8__R__)‐4,8‐Dimethyldecanal (1) were synthesized by starting from (__R__)‐citronellic acid (2a), methyl (__S__)‐3‐hydroxy‐2‐methylpropanoate (3a), and (__S__)‐2‐methyl‐1‐butanol (4a).

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**Pheromonsynthesen, LXXIII. ‐ Neue Synthese von (4__R__,8__R__)‐4,8‐Dimethyldecanal, dem Aggregationspheromon von __Tribolium castaneum__, und seines (4__R__,8__S__)‐Isomeren** Die Synthese der Titelverbindungen (4__R__,8__R__)‐**1** und (4__R__,8__S__)‐**1** aus (__R__)‐Citronellsäure [(__R__)‐**