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Pheromone syntheses, LXXIII. New synthesis of (4R,8R)-4,8-dimethyldecanal, the aggregation pheromone oftribolium castaneum, and its (4R,8S)-isomer

✍ Scribed by Mori, Kenji ;Kato, Minoru ;Kuwahara, Shigefumi

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
327 KB
Volume
1985
Category
Article
ISSN
0947-3440

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✦ Synopsis

Pheromonsynthesen, LXXIII. ‐ Neue Synthese von (4__R__,8__R__)‐4,8‐Dimethyldecanal, dem Aggregationspheromon von Tribolium castaneum, und seines (4__R__,8__S__)‐Isomeren

Die Synthese der Titelverbindungen (4__R__,8__R__)‐1 und (4__R__,8__S__)‐1 aus (R)‐Citronellsäure [(R)‐2] wird beschrieben. Die Anwendung der Kolbe‐Elektrolyse ist der Schlüsselschritt der Synthese.

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