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Phenylated Dihydrofurans. Photo- and Acid-Catalyzed Rearrangements and Intermediacy in Cyclopropyl Ketone Cleavage

โœ Scribed by Boykin, David W.; Lutz, Robert E.

Book ID
126150066
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
259 KB
Volume
86
Category
Article
ISSN
0002-7863

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Protonation by gaseous Hi, CnHi (n=1,2), s-C3HG and t-C H+ 49 cations promotes rearrangement of cyclopentane-and cyclohexanecarboxaldehyde to cyclohexanone and cyclo~entylmethyl ketone, respectively. The reaction was investigated by radiolytic and mass spectrometric methods. The mechanism of the aci