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Formation of benzoic acid in the palladium(II) catalyzed cleavage of phenyl-antimony and phenyl-phosphorus groups of Ph3Sb and Ph3P

✍ Scribed by Anil B. Goel; H.J. Richards; J.H. Kyung


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
133 KB
Volume
25
Category
Article
ISSN
0040-4039

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Rate constants and products are reported for the aqueous decomposition (pH 0 ± 14) of phenyl N-(phenoxycarbonyl)sulfamate (pK a 1.18) at 50 8C. The pH ± rate profile indicates a rate law that includes three terms: two pH-independent terms, k a in acid and k p around neutral pH, with k a b k p , and