Phenoxyl radical formation and reversible addition with nitric oxide and 2,6-DI-tert-butylphenols
β Scribed by Allan L. Wilcox; Edward G. Jansen
- Book ID
- 113386082
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 140 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0891-5849
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π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Ε½ t . Ε½ . The oxidation of 2,6-di-tert-butylphenol with tert-butylhydroperoxide Bu O H has been studied using polymer XAD 2 4 anchored salicylaldoxime, 1,3-propylene-bis-salicylaldimine and o-phenylene-bis-salicylaldimine complexes of molybdenum and vanadium in acetonitrile. The predominant product
Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.