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Phencyclone Diels-Alder adducts as a new crystalline host. Role of CH···π and CH···O interactions

✍ Scribed by Masashi Eto; Koji Setoguchi; Akiko Harada; Eri Sugiyama; Kazunobu Harano

Book ID: 104260361
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 210 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02283-7

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✦ Synopsis

A series of crystalline host compounds, which have a bicyclo[2.2.1]heptene-7-one system, has been synthesized and their inclusion behavior has been investigated. The cycloadduct of phencyclone and N-naphthylmaleimide forms a 1:1 crystalline inclusion complex with 2-butanone. The crystal structure indicates the presence of weak lattice forces supported by C-H...rt and C-H...O interactions.

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