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(Phenalene)chromium Tricarbonyl Complexes. Synthesis, Structure, and Thermal Rearrangements

✍ Scribed by Akhmedov, N. G.; Malyugina, S. G.; Mstislavsky, V. I.; Oprunenko, Yu. F.; Roznyatovsky, V. A.; Ustynyuk, Yu. A.; Batsanov, A. S.; Ustynyuk, N. A.

Book ID
126072314
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
316 KB
Volume
17
Category
Article
ISSN
0276-7333

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## Abstract The Cr(CO)~3~‐complexed η6‐phenylpropargylic alcohols 3 react in a displacement rearrangement with thionyl chloride or chlorodiphenylphosphane to give the chloro‐ or phosphoryl allenyl substituted η6‐phenyl complexes 4 and 6, respectively. In the X‐ray crystal structure of the novel org