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Phase transitions in CuZrF6 and CrZrF6: A Mössbauer and EPR study of local and cooperative Jahn-Teller distortions

✍ Scribed by C. Friebel; J. Pebler; F. Steffens; M. Weber; D. Reinen


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
768 KB
Volume
46
Category
Article
ISSN
0022-4596

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Mössbauer study of the phase transitions
✍ L. Asch; I. Dézsi; T. Lohner; B. Molnár 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 205 KB

The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa