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Phase transition in crystalline p-polyphenyls: Heat capacity of 4,4‴-difluoro-p-quaterphenyl

✍ Scribed by Kazuya Saito; Yasuhisa Yamamura; Hideki Saitoh; Haruo Matsuyama; Koichi Kikuchi; Isao Ikemoto

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 338 KB
Volume: 92
Category: Article
ISSN: 0038-1098
DOI: 10.1016/0038-1098(94)90485-5

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The heat capacity of crystalline bis(4-chlorophenyl)sulfone was measured from the temperature \(T=14\) to \(T=300 \mathrm{~K}\) by adiabatic calorimetry. An incommensurate phase transition was detected as a second-order type of heat-capacity anomaly at \(T=(148.5 \pm 0.5) \mathrm{K}\). The molar ent