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Phase Transition and Thermal Decomposition of [Cd(H2O)6](BF4)2

✍ Scribed by E. Mikuli; A. Migdał-Mikuli; R. Gajerski

Book ID
110345795
Publisher
Springer Netherlands
Year
2002
Tongue
English
Weight
58 KB
Volume
68
Category
Article
ISSN
0022-5215

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✍ L. Asch; I. Dézsi; T. Lohner; B. Molnár 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 205 KB

The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa