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Phase transition and its connection with molecular motions in [Cu(NH3)5](BF4)2

✍ Scribed by A. Migdał-Mikuli; E. Mikuli; Ł. Hetmańczyk; E. Ściesińska; J. Ściesiński

Book ID
103837299
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
316 KB
Volume
792-793
Category
Article
ISSN
0022-2860

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The phase transition in [Cr(NH 3 ) 6 ](BF 4 ) 3 at T h c ¼ 238:42 K (on heating) and at T c c ¼ 237:93 K (on cooling) was determined by differential scanning calorimetry (DSC). Fourier transform far infrared (FT-FIR) and middle infrared (FT-MIR) spectra were measured in the temperature range of 20 -