Phase transfer Pd(0) catalyzed polymerization reactions
β Scribed by Coleen Pugh; Virgil Percec
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 787 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
Mercaptans react with triiron dodecacarbonyl or dicobalt octacarbonyl, under phase transfer catalysis conditions, to give hydrocarbons in good yields. Phase transfer catalysis ls2 is a valuable method for effecting a variety of reactions involving organometallic compounds as stoichiometric reagents
Catalytic asymmetric Darzens reaction promoted by a chiral phase-transfer catalyst derived from cinchonine is described. The desired o~,[I-epoxy ketones were obtained by use of ct-chloro acyclic and cyclic ketones as substrates with moderate to high enantiomeric excesses under mild reaction conditio