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Perturbed Equilibria and Statistical Energy Redistribution in a Gas-Phase SN2 Reaction

โœ Scribed by Craig, S. L.


Book ID
121157916
Publisher
American Association for the Advancement of Science
Year
1997
Tongue
English
Weight
163 KB
Volume
276
Category
Article
ISSN
0036-8075

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Competition between substitution (SN2),
โœ J. Haib; D. Stahl ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 671 KB

The competition between substitution (sN2), elimination (E2) and additiorrelimination (AE) reactions in the gas phase has been studied by using OH-and NH,as nucleophiles reacting with esters of acetylenedicarboxylic acid of general formula RO(O)CCZCC(O)OR'. By selectively varying R and R' it was pos