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SN2 reaction profiles in the gas phase and aqueous solution

โœ Scribed by Chandrasekhar, Jayaraman; Smith, Scott F.; Jorgensen, William L.


Book ID
118055814
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
311 KB
Volume
106
Category
Article
ISSN
0002-7863

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This calculation introduces a promising way to catalyze gas-phase S N 2 reactions at a unimolecular level by using an excess electron (EE) as an ''electron solvent''. The EE participation leads to very favorable energetics for the reaction, by neutralizing the created positive charge as the reaction