Perturbation theory and the radial distribution function of fluids with nonspherical potentials
โ Scribed by William R. Smith; William G. Madden; Donald D. Fitts
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 306 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
A perturbation expupansion for the radial distribution function of fluids with nonsphericzJ pair potentials is discussed.
Numerical calculations are presented for dipolar hard-sphere and quadrupolar hard-sphere fluids. Agreement with the computer simulation results is excellent, even at high dipole and quadrupole moments.
๐ SIMILAR VOLUMES
A method for calculating the entropy and the chemical potential of fluids and solids from the radial free-space distribution function (RFSDF) is proposed. The free volume is obtained from the RFSDF by eliminating the arbitrary definition ofa cell and the imposition of a cut-off distance that were us
Second-order pcrturbatron rheory rs used fo calculate the sphcruA harmoruc coefficients of the angular pau correlatton function and the drelectnc constant and Kerr paramctcr of Stockmayer thuds wtth dtpoles and quadrupoles The results mdrcate that the drclectrrc constant and the Kerr parameter both