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Second-order perturbation theory for the dielectric constant and kerr factor of fluids with dipoles and quadrupoles

✍ Scribed by Sohail Murad


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
300 KB
Volume
72
Category
Article
ISSN
0009-2614

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✦ Synopsis


Second-order pcrturbatron rheory rs used fo calculate the sphcruA harmoruc coefficients of the angular pau correlatton function and the drelectnc constant and Kerr paramctcr of Stockmayer thuds wtth dtpoles and quadrupoles The results mdrcate that the drclectrrc constant and the Kerr parameter both decrease raptdly wrth mcrensmg qundrupole moment for any g~vrn drpolc moment Thcsc results confirm the recent conclusrons of Patey usmg mtegral equatton methods. The effeet of long-range forces is also mvestrgated