Perturbation in the C 3Π(v′ = 1) state of A1N studied by laser spectroscopy
✍ Scribed by Maarten Ebben; J.J. ter Meulen
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 483 KB
- Volume
- 177
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
We report the LIF spectrum of the C 'lI( u' = 1) CX 311( Y" ~0) transition in the AlN molecule. Laser vaporization in combination with supersonic expansion and laser-induced fluorescence are used to produce and detect the AIN molecules. The mole0 ular constants and electronic lifetimes of the C state are determined. Predissociation and an accidental perturbation are discussed and compared to an ab initio potential calculation of the electronic states.
- mroduction
📜 SIMILAR VOLUMES
The A 1 P -X 1 S / system of the PN molecule has been reexamined via high resolution conventional spectroscopy, at higher rotational J-values than those in previous studies. It is shown that perturbations occurring in the A 1 P (£ Å 0 to 3) levels give access to information concerning the (e 3 S 0 ,
PH3 have been brought in resonance with CO2 laser lines. using an intracavity Stark cell. Accurate values of the dipole moments &=, = 0.574Ort 0.0002 D and p,\_=, = 0.5781\* 0.0001 D) and of the transition frequencies have been obtained.
The fourth positive \(\left(A^{\prime} \Pi-X^{1} \Sigma^{+}\right.\)) system of the carbon monoxideisotopomers \({ }^{12} \mathrm{C}^{18} \mathrm{O}\) and \({ }^{13} \mathrm{C}^{18} \mathrm{O}\) excited in the anode column of a hollow-cathode discharge tube was recorded in the spectral region \(1710