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Peroxy esters. 7. Base-catalyzed reaction of 5-(acylmethyl)-2,5-di-tert-butyl-4-oxa-2-cyclopentenones derived selectively from acid catalysis of 2,6-di-tert-butyl-p-peroxyquinol acetates

✍ Scribed by Nishinaga, Akira; Nakamura, Koichi; Matsuura, Teruo

Book ID: 126964102
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 640 KB
Volume: 47
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00347a010

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Base-catalyzed decomposition of 3,5-di-t-butyl-4-hydroxybenzoic esters of p-peroxyquinols derived from 2,6-di-t-Butylphenols

✍ A. Nishinaga; K. Nakamura; T. Matsuura 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 197 KB

In a previous paper,' we reported a novel base-catalyzed rearrangement of R-peroxyquinol esters derived from 2,6-di-t-butylphenols leading to quinoxyacetic acid derivatives, where the peroxy bond cleaves even below -60 "C. Nature of the peroxy bond cleavage has been remained n