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PEROXIDE-CATALYZED ADDITION OF TRICHLOROSILANE TO 1-OCTENE

✍ Scribed by Sommer, L. H.; Pietrusza, E. W.; Whitmore, F. C.

Book ID
120837390
Publisher
American Chemical Society
Year
1947
Tongue
English
Weight
142 KB
Volume
69
Category
Article
ISSN
0002-7863

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## Abstract The Pd‐catalyzed addition of carbon monoxide and carbon tetrachloride to 1‐octene gave coadduct [alkyl 2‐(2, 2, 2‐trichloroethyl)octanoate] as the major product in supercritical carbon dioxide by using pyridine as the base. It was found that the selectivity and the yield of coadduct wer