Peroxidase catalyzed polymerization of phenol
β Scribed by Palligarnai T. Vasudevan; Luting Olivia Li
- Book ID
- 112893899
- Publisher
- Springer-Verlag
- Year
- 1996
- Tongue
- English
- Weight
- 484 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0273-2289
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π SIMILAR VOLUMES
Polymers produced by horseradish-peroxidase-catalyzed coupling of phenols have been explored as potential substitutes for phenol-formaldehyde resins. To overcome low substrate solubilities and product molecular weights in water, enzymatic polymerizations in aqueous-organic mixtures have been examine
Phenolic polymerization was carried out by enzymatic catalysis in organic media, and its kinetics was studied by using high-pressure liquid chromatography (HPLC). Phenols and aromatic amines with electron-withdrawing groups could hardly be polymerized by HRP catalysis, but phenols and aromatic amine
## Abstract Halogenated phenols and bisphenols are recognized as being recalcitrant in conventional biological treatments. The current research evaluated lignin peroxidaseβcatalyzed oxidation and polymerization as a potential alternative for their detoxification. Gel permeationβHPLC analysis demons