Peroxidase-Catalyzed Oxidative Polymerization of Bisphenols
โ Scribed by Uyama, Hiroshi; Maruichi, Naoyuki; Tonami, Hiroyuki; Kobayashi, Shiro
- Book ID
- 124149543
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 86 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1525-7797
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๐ SIMILAR VOLUMES
Ortho-, meta-, and para-phenylenediamines were polymerized using hydrogen peroxide as an oxidant and horseradish peroxidase as a catalyst in mixed solvents of 1,4-dioxane and water. The yield of the polymers was strongly dependent on solvent composition, and maximum yields were obtained at 15-30% 1,
Enzymatic oxidative polymerization of p-alkylphenols using horseradish peroxidase as catalyst has been carried out in two polymerization solvent systems: a mixture of phosphate buffer (pH 7) and 1,4-dioxane, and a reverse micellar solution, yielding powdery polymeric materials. The polymer yield was