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Permethyltitanocene-bis(trimethylsilyl) acetylene, an efficient catalyst for the head-to-tail dimerization of 1-alkynes

✍ Scribed by Vojtech Varga; Lidmila Petrusová; Jiří Čejka; Vladimír Hanuǔs; Karel Mach


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
546 KB
Volume
509
Category
Article
ISSN
0022-328X

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✍ Kathleen Schmohl; Matthias Blach; Helmut Reinke; Rhett Kempe; Hartmut Oehme 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 363 KB 👁 3 views

The regiospecifity of the dimerization of the transient 2-(2-cyclobutane (13) was obtained. 1,1-Bis(trimethylsilyl)-2-(2,4,6-trimethoxyphenyl)silene (18), similarly made by a methoxyphenyl)-1,1-bis(trimethylsilyl)silene (6), synthesized by base-initiated trimethylsilanolate elimination from (2-modif