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Permethyl-4,4′-bis-Δ1,2-pyrazolinylibene (4) the synthesis and x-ray chystallographic structure of a highly crowded olefin

✍ Scribed by Richard J. Bushby; Michael D. Pollard; Walter S. McDonald


Book ID
104246102
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
198 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis


In recent years there has been considerable interest in the synthesis and properties of highly crowded olefins.' Much of this effort has been concentrated on obtaining tetraHbuty1 ethylene (L). Whilst this has remained an elusive goal some olefins which approach its high degree of steric crowding (for example 2 and 3) have been obtained.


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Synthesis and X-ray structure of a novel
✍ Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A. K. Howard 📂 Article 📅 1999 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 171 KB

## Abstract Photolysis of 1,2‐dithiole‐3‐thione derivative 1 results in the formation of the 1,2,4‐trithiolane derivative 2, the structure of which was established by single crystal X‐ray analysis. Interesting bond delocalisation is observed in the molecular structure. A mechanism involving dimeris