𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and X-ray structure of a novel 1,2,4-trithiolane

✍ Scribed by Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A. K. Howard

Publisher
Journal of Heterocyclic Chemistry
Year
1999
Tongue
English
Weight
171 KB
Volume
36
Category
Article
ISSN
0022-152X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Photolysis of 1,2‐dithiole‐3‐thione derivative 1 results in the formation of the 1,2,4‐trithiolane derivative 2, the structure of which was established by single crystal X‐ray analysis. Interesting bond delocalisation is observed in the molecular structure. A mechanism involving dimerisation of 1 followed by loss of sulfur is proposed.

πŸ“œ SIMILAR VOLUMES

A Short Synthesis of 3,5-Dimethyl-1,2,4-
A Short Synthesis of 3,5-Dimethyl-1,2,4-trithiolane
✍ Paul Dubs; Martin Joho πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 174 KB

## Abstract A short synthesis of 3,5‐dimethyl‐1,2,4‐trithiolane (**1**), a well‐known constituent of processed meat, is described.