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Permanganate oxidation of N6,N6,8-trisubstituted-2′,3′,5′- tri-o-acetyladenosines

✍ Scribed by Tetsuo Kato; Shuichi Ogawa; Isoo Ito


Book ID
104234196
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
259 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis


Oxidation of 2 ',3', 5'-tri-0-acety2. derivatives of N6,iV6-dialkyl-adenosincsf3a-gl with KMnO I, in 50% AcOH gave both the mono(5a-gl and dideaZkyZ derivative.s(ba-cl ; it was conclusively proved that one and two methyZene groups of the title nucZeosidesl.,a-g) in the a position to the exocyclic nitrogen atom were simultaneously oxidized.


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