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Syntheses and structures of two new M6Li8(N3)a6 cluster-unit based compounds: Cs4Re6S8(N3)6·H2O and Na2Mo6Br8(N3)6·2H2O

✍ Scribed by Guillaume Pilet; Stéphane Cordier; Stéphane Golhen; Christiane Perrin; Lahcène Ouahab; André Perrin


Book ID
114370772
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
369 KB
Volume
5
Category
Article
ISSN
1293-2558

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✍ Zhyldyz S. Kozhomuratova; Yuri V. Mironov; Michael A. Shestopalov; Irina V. Dreb 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB

## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~·6H~2~O and rh