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PERMANGANATE DECOMPOSITION IN ALKALINE MEDIA

โœ Scribed by Ferguson, R. H.; Lerch, Wm.; Day, J. E.

Book ID
127023360
Publisher
American Chemical Society
Year
1931
Tongue
English
Weight
734 KB
Volume
53
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Permanganate oxidation of unsaturated al
Permanganate oxidation of unsaturated alcohols in alkaline media
โœ Miklรณs Jรกky; Edit Simon-Trompler ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 130 KB

## Abstract A study was made on permanganate oxidation of olefinic and acetylenic alcohols in aqueous alkali media. Deprotonation constants of alcohols can be calculated from the kinetic data. The rate constant of alkoxide group oxidation exceeded that of the unsaturated bond. For oxidation of the

OXIDATION OF ALDEHYDES WITH PERMANGANATE
OXIDATION OF ALDEHYDES WITH PERMANGANATE IN ACIDIC AND ALKALINE MEDIA
โœ M. Jรกky; J. Szammer ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 157 KB ๐Ÿ‘ 2 views

The oxidation mechanism of aldehydes with permanganate was studied in acidic and alkaline media on acetaldehyde, propionaldehyde, pivalaldehyde (2,2ะˆ-dimethylpropanal) and chloral substrates. On addition of water to acetaldehyde dissolved in organic solvents the rate increased, and therefore it may