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Periselective intramolecular cycloaddition of allene-1,3-dicarboxylates. Unusual structural feature of [2 + 2] cycloadducts

โœ Scribed by Yoshida, Mitsutaka.; Hidaka, Yukari.; Nawata, Yoshiharu.; Rudzinski, Jerzy M.; Osawa, Eiji.; Kanematsu, Ken.


Book ID
127392256
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
785 KB
Volume
110
Category
Article
ISSN
0002-7863

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8icyclo[3.2.l]octa-3,6-dien-2-ones photoisomerize to ketenes (J + 2; ,4 + 0): When the ketene is hfghly substituted, as in the octamethyl derivative ,$' or is unusually reactive, as in the chloroketene :), intramolecular cycloaddition (GZs + n2a) competes successfully with attack by external nucleop