The photoisomerization of 2-methylenebic
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Harold Hart; Masayuki Kuzuya
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Article
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1974
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Elsevier Science
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French
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8icyclo[3.2.l]octa-3,6-dien-2-ones photoisomerize to ketenes (J + 2; ,4 + 0): When the ketene is hfghly substituted, as in the octamethyl derivative ,$' or is unusually reactive, as in the chloroketene :), intramolecular cycloaddition (GZs + n2a) competes successfully with attack by external nucleop