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Acid-Catalyzed Domino Meinwald Rearrangement of Epoxides/Intramolecular [3+2] Cross-Cycloaddition of Cyclopropane-1,1-dicarboxylates

✍ Scribed by Zhu, Wenju; Ren, Jun; Wang, Zhongwen


Book ID
121729805
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
492 KB
Volume
2014
Category
Article
ISSN
1434-193X

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Lewis Acid-Catalyzed [3+4] Annulation of
✍ Olga A. Ivanova; Ekaterina M. Budynina; Alexey O. Chagarovskiy; Alexey E. Kaplun 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 348 KB 👁 2 views

## Abstract A novel Lewis acid‐catalyzed [3+4] annulation of 2‐(heteroaryl)cyclopropane‐1,1‐dicarboxylates with cyclopentadiene is reported. This reaction proceeds __via__ an electrophilic attack of the Lewis acid‐activated donor‐acceptor cyclopropane onto cyclopentadiene followed by Friedel–Crafts