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Perfluoroalkyl-selenation of olefins

โœ Scribed by Kenji Uneyama; Kouichi Kitagawa; Kouichi Kitagawa

Book ID
104225408
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
223 KB
Volume
32
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Perfluoroalkyl-selenation of olefins has been performed by the reaction of diphenyl diselenide with sodium borohydride followed with perfluoroalkyl halides (RfX) and olefins where one electron transfer from phenylseleno anion to RfX occurs, generating perfluoroalkyl and phenylseleno radicals.

๐Ÿ“œ SIMILAR VOLUMES

Perfluoroalkyl-chalcogenation of olefins
Perfluoroalkyl-chalcogenation of olefins
โœ Kenji Uneyama; Masatomi Kanai; Kouichi Kitagawa ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 40 KB

Perfluoroalkyl-chalcogenation of olefins has been performed by the reaction of chalcogenide anions with perfluoroalkylhalides (IV-X) in the presence of olefins. Chalcogenide anion cleaves reductively the carbon-halogen bond of Bf-X, generating perfluoroalkyl radicals which undergo addition to C=C bo