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Electrocatalytic fluoroalkylation of olefins. Perfluoroalkylation of 2-vinylpyridine

โœ Scribed by Khrizanforov, M. N.; Gryaznova, T. V.; Mikhailov, D. Yu.; Budnikova, Yu. H.; Sinyashin, O. G.

Book ID
120584609
Publisher
Springer
Year
2012
Tongue
English
Weight
204 KB
Volume
61
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES

Electrocatalytic fluoroalkylation of ole
Electrocatalytic fluoroalkylation of olefins
โœ D. Yu. Mikhaylov; T. V. Gryaznova; Yu. G. Budnikova; O. G. Sinyashin ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Springer ๐ŸŒ English โš– 187 KB
Perfluoroalkyl-selenation of olefins
Perfluoroalkyl-selenation of olefins
โœ Kenji Uneyama; Kouichi Kitagawa; Kouichi Kitagawa ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 223 KB

Perfluoroalkyl-selenation of olefins has been performed by the reaction of diphenyl diselenide with sodium borohydride followed with perfluoroalkyl halides (RfX) and olefins where one electron transfer from phenylseleno anion to RfX occurs, generating perfluoroalkyl and phenylseleno radicals.

Perfluoroalkyl-chalcogenation of olefins
Perfluoroalkyl-chalcogenation of olefins
โœ Kenji Uneyama; Masatomi Kanai; Kouichi Kitagawa ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 40 KB

Perfluoroalkyl-chalcogenation of olefins has been performed by the reaction of chalcogenide anions with perfluoroalkylhalides (IV-X) in the presence of olefins. Chalcogenide anion cleaves reductively the carbon-halogen bond of Bf-X, generating perfluoroalkyl radicals which undergo addition to C=C bo