Perchloropropa-1,2-diene, a Highly Reactive Allene

✍ Scribed by Prof. Dr. A. Roedig; Dr. G. Märkl; Dipl.-Chem. B. Heinrich

• Book ID: 101546876
• Publisher: John Wiley and Sons
• Year: 1963
• Tongue: English
• Weight: 141 KB
• Volume: 2
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.196300472

✦ Synopsis

CH30)3Si]3N, b.p. 110 OC/3 mm Hg; [(CH3)(CH30)2Si]3N, b. p. 90 "C/4 mm Hg; or [(CH3)(C2H3)(i-C3H,O)Si]3N, b.p. 108 "C/l mm Hg. On account of the complete shielding effect of isopropyl groups, [(i-C3H70)3Si]3N, m. p. 267 "C, b. p.

284OC, which is almost spherical, is distinguished by its surprising resistance to hydrolysis.