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A highly strained bicyclic allene-bicyclo(3.2.1)octa-2,3-diene intermediate

✍ Scribed by P. Mohanakrishnan; S.R. Tayal; R. Vaidyanathaswamy; D. Devaprabhakara


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
96 KB
Volume
13
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Bicyclic allenes : Generation and trappi
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SUMMA??Y: Treatment of 3-bromo-6,7-benzobicyclo c3.2.11 octa-2,3-diem? (9) with potassium tert.-butoxide produces the strained bicyclic allene (10) which is trapped by 1,3-diphenylbenzo[c]furan (DBI) to give five isomeric cycloadducts. In the absence of DBI, allene (10) gave rise to enol ether ( 18)

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