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Pentamethylcyclopentadienyl (.eta.5-C5(CH3)5) vs. cyclopentadienyl (.eta.5-C5H5). A comparison of electronic influences for metallocenes with fac-a3b2c, fac-a3b3, and cis-a3b2 ligand geometry based on cobalt-59 NQR spectroscopy

✍ Scribed by Miller, E. J.; Landon, S. J.; Brill, T. B.


Book ID
125901418
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
831 KB
Volume
4
Category
Article
ISSN
0276-7333

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Complexes of the (Tetramethylcyclobutadi
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The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th