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Pentadecamer 2,5-Dipropoxy-1,4-phenylenevinylene

✍ Scribed by Herbert Meier; Dirk Ickenroth

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
125 KB
Volume
2002
Category
Article
ISSN
1434-193X

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## Abstract Poly(2,5‐dipropargyloxy‐1,4‐phenylenevinylene) (PDPPV) and its copolymers were prepared as thin films via the organic‐soluble and water‐soluble precursor routes. Elimination and crosslinking reactions could be controlled by the temperature. Crosslinked PDPPV is stable up to 450°C. The c

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## Abstract Oligomers of 2,5‐dialkyl‐1,4‐phenylenevinylenes (DR‐OPV, R = C~4~H~9~, C~7~H~15~, C~10~H~21~ and C~6~H~11~) (CyH) were prepared via metathesis polycondensation of the respective 2,5‐dialkyl‐1,4‐divinylbenzenes. The synthesis of the monomers is described. The highly active metal‐alkylide