𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and characterization of poly(2,5-dipropargyloxy-1,4-phenylenevinylene) and its copolymers with 1,4-phenylenevinylene

✍ Scribed by Hong-Ku Shim; Do-Hoon Hwang; Chong-Bok Yoon

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
393 KB
Volume
197
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Poly(2,5‐dipropargyloxy‐1,4‐phenylenevinylene) (PDPPV) and its copolymers were prepared as thin films via the organic‐soluble and water‐soluble precursor routes. Elimination and crosslinking reactions could be controlled by the temperature. Crosslinked PDPPV is stable up to 450°C. The conductivity values of undrawn and drawn FeCl~3~‐doped PDPPV films are 5.0 × 10^−2^ and 2.0 × 10^−1^ Sċcm^−1^, respectively. The third‐order nonlinear optical susceptibility, χ^(3)^, for the PDPPV film was investigated by degenerate four‐wave mixing (DFWM) technique at 602 nm wavelength, and found to be 2.3 × 10^−10^ esu.

📜 SIMILAR VOLUMES

The substitution effects of donor and ac
The substitution effects of donor and acceptor on properties of poly(1,4-phenylenevinylene) derivatives. Syntheses of poly(2-methoxy-5-methylsulfinyl-1,4-phenylenevinylene) and its copolymers
✍ Chong-Bok Yoon; Hong-Ku Shim 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 354 KB 👁 1 views

## Abstract Electron donor and acceptor substituted poly(2‐methoxy‐5‐methylsulfinyl‐1,4‐phenylenevinylene) (PMMSPV) and a series of copolymers containing 1,4‐phenylenevinylene (PV) units were synthesized via the water‐soluble precursor pathway and cast into films. The electrical conductivity of FeC

Synthesis and characterization of the so
Synthesis and characterization of the soluble fluorescent poly[2-decyloxy-5-(2′-(6′-dodecyloxy)naphthyl)-1,4-phenylenevinylene]
✍ Hung-Te Chang; Hsun-Tsing Lee; Mou-Yung Yeh 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB 👁 1 views

## Abstract A new soluble fluorescent polymer, poly[2‐decyloxy‐5‐(2′‐(6′‐dodecyl‐oxy)naphthyl)‐1,4‐phenylenevinylene] (DDN‐PPV), with no tolane‐bisbenzyl (TBB) structure defects is prepared by the dehydrohalogenation of 1,4‐bis(bromomethyl)‐2‐decyloxy‐5‐(2′‐(6′‐dodecyloxy)naphthyl)benzene (as monom

Photoluminescence of poly(1,4-phenylenev
Photoluminescence of poly(1,4-phenylenevinylene) derivatives in solution and film
✍ Min Zheng; Fenglian Bai; Daoben Zhu 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB 👁 2 views

Four dialkoxy-substituted poly(1,4-phenylenevinylene) (PPVs) and four copolymers of poly [(2-methoxy-5-(2'ethylhexloxy)-p-phenylene vinylene)] (MEH-PPV) and non-substituted PPV were synthesized. The comparative photoluminescence properties of the resulting polymers are reported. In dilute solution t