Pentacyclic triterpene synthesis. III. Preparation of an optically active synthon for rings A and B
β Scribed by John S. Dutcher; Clayton H. Heathcock
- Book ID
- 104234702
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 132 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In previous communications, we have outlined syntheses of decalinic sub-
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Optically active trans-4-(tert-butyldimethylsiloxymethyl)-5-(tert-butyldimethylsiloxy)-2-cyclohexenone (2) has been synthesized in 25% overall yield starting from easily available 1,4-bis(benzyloxy)-2,3-epoxy butane (3). The enone 2 reacts with excellent stereoselectivity with RCu(CN)Li thus working
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