Pentacyano- N , N -Dimethylaniline in the Excited State. Only Locally Excited State Emission, in Spite of the Large Electron Affinity of the Pentacyanobenzene Subgroup
โ Scribed by Zachariasse, Klaas A.; Druzhinin, Sergey I.; Galievsky, Victor A.; Demeter, Attila; Allonas, Xavier; Kovalenko, Sergey A.; Senyushkina, Tamara A.
- Book ID
- 126126082
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 768 KB
- Volume
- 114
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
The formation of an intramolecular excited complex stale in 4-(9-anthrylmeLhyl)-N.N-dimeLhylaniline was investigated at h@ p-w\_ A change in the kinetics from thermodyoamic conlrol to kinetic control VIZ observed m ethyl elhcr solvent In loluene tie pr-is kinclically con~olled over the whole pressur
The kinetics of formation of an excited charge-transfer (CT) state in ?-(9-antllrvl)\_N,h'-di~iet~~~laniline have been studied by means of steady-state and nanosecond time-resolved fh~orcsctnce. It is concluded rhat the escited CT state is formed irreversibly at room temperature in ethyl acetate on