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Pentacoordinate nickel(II) complexes of monodentate ligands. Complexes of trimethylstibine

✍ Scribed by Ludmann, M. F.; Dartiguenave, M.; Dartiguenave, Y.

Book ID
126282267
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
979 KB
Volume
16
Category
Article
ISSN
0020-1669

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## Abstract Terminal acetylenes react with __cis__‐RuMe~2~(PMe~3~)~4~ to form the bis(acetylido) complexes __cis__/__trans__‐Ru(C≑CR)~2~(PMe~3~)~4~ in good yield. The structures of __trans__‐2 (R = Ph), __cis__‐3 (R = __p__‐C~6~H~4~‐OMe), __trans__‐4 (R = __p__‐C~6~H~4~‐Me), __cis__‐6 (R = Me), __t