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Pentachlorothiophenolato- and diphenylpentachlorophenylphosphine complexes of rhodium(I) and platinum(II)

✍ Scribed by R.D.W. Kemmitt; G.D. Rimmer

Book ID
118909429
Publisher
Elsevier Science
Year
1973
Weight
327 KB
Volume
35
Category
Article
ISSN
0022-1902

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Rhodium(I), iridium(I), palladium(lI) and platinum(II) complexes of the phosphinoamide ligands, Ph2PCH2CONHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized by using conductivity data, i.r., 1H and31P(H) n.m.r, spectral data. Reaction of the ligands with MCI(PPh3) 3 and MCI(CO)(PPh