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Peculiarities in the polarographic reduction of carbon-metal bond in alkyl derivatives of cobalt-schiff base complex

✍ Scribed by I. Ya. Levitin; M. E. Vol'pin


Book ID
112422832
Publisher
Springer
Year
1972
Tongue
English
Weight
189 KB
Volume
21
Category
Article
ISSN
1573-9171

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Double asymmetric synthesis: Palladium c
✍ J.P. Genet; N. Kopola; S. Juge; J. Ruiz-Montes; O.A.C. Antunes; S. Tanier πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 270 KB

A new double asymmetric induction in carbon-carbon bond formation is -achieved by the use of palladium chiral complexes in the alkylation of chiral Schiff bases1 derived from glycine. High diastereoisomeric excesses are obtained (90-999) using N.N-cyclohexylsulfamoylisobornyl derivatives and DIOP as