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Mechanistic investigation of carbon-carbon bond formation in the reduction of alkyl halides by organonickel complexes in aqueous solution

✍ Scribed by Bakac, Andreja.; Espenson, James H.

Book ID
120398428
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
679 KB
Volume
108
Category
Article
ISSN
0002-7863

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Carboncarbon bond formation in neutral
Carboncarbon bond formation in neutral aqueous medium by modification of the Nozaki–Hiyama reaction
✍ Károly Micskei; Attila Kiss-Szikszai; Julianna Gyarmati; Csongor Hajdu 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 86 KB

A carbon carbon bond forming reaction has been developed by modifying the Nozaki-Hiyama reaction using a chromium(II)-aminopolycarboxylate complexes in a neutral aqueous medium at room temperature. Aldehydes and ketones can be coupled with aralkyl and aryl halides in good yields.