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Pd(II) inhibition during hexacyanoferrate(III) oxidation of sugars: A kinetic study

✍ Scribed by Pankaj Bajpai; Anju Shukla; Santosh K. Upadhyay

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
374 KB
Volume
28
Category
Article
ISSN
0538-8066

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✦ Synopsis

An inhibition effect of PdCI, on the rate of oxidation of sugars, by alkaline hexacyanoferrate( 111) has been observed The order of reactions in hexacyanoferrate(Il1) and OH-is zero and unity, respectively. while that in sugars decreases from unity at higher sugar concentration The kinetic data and spectrophotometric evidence support the formation of (Pd" -(sugar)] a n d (Pd" -sugar),] complexes and their resistance to react with Fe(CN)i-0 1996

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