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[Pd(Ar-BIAN)(alkene)]-Catalyzed Highly Chemo-, Regio-, and Stereoselective Semihydrogenation of 1,2-Allenyl Phosphonates and Related Compounds.

✍ Scribed by Hao Guo; Zilong Zheng; Fei Yu; Shengming Ma; Alexandre Holuigue; Dorette S. Tromp; Cornelis J. Elsevier; Yihua Yu


Publisher
John Wiley and Sons
Year
2006
Weight
30 KB
Volume
37
Category
Article
ISSN
0931-7597

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[Pd(Ar-BIAN)(alkene)]-Catalyzed Highly C
✍ Hao Guo; Zilong Zheng; Fei Yu; Shengming Ma; Alexandre Holuigue; Dorette S. Trom πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 109 KB

Allenes are an important class of compounds with many applications in organic chemistry. [1,2] However, the hydrogenation of allenes is challenging, as there are issues of chemo-, regio-, and stereoselectivity to be addressed (Scheme 1). [2d] Only a very limited number of studies in this area have b