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Pd-Catalyzed Regio- and Stereoselective Cyclization—Heck Reaction of Monoesters of 1,2-Allenyl Phosphonic Acids with Alkenes.

✍ Scribed by Fei Yu; Xiongdong Lian; Shengming Ma


Publisher
John Wiley and Sons
Year
2007
Weight
45 KB
Volume
38
Category
Article
ISSN
0931-7597

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Allenes are an important class of compounds with many applications in organic chemistry. [1,2] However, the hydrogenation of allenes is challenging, as there are issues of chemo-, regio-, and stereoselectivity to be addressed (Scheme 1). [2d] Only a very limited number of studies in this area have b